Optical basicity

WebJun 25, 2024 · The optical basicity of the glass has been estimated and it has the values from 1.11 to 1.31 with varying vanadium content from zero to 5 mol%. Static dielectric … For oxides, MO (M = Mg, Ca, Sr, Ba), the basicity moderating parameter of M gover… Arguments are presented justifying the use of fluoride optical basicity values (e.g… The optical basicity trend in alkali borate glasses has been studied in detail [2,13-… The basicity of the oxidic groups AlO 4 5−, SiO 4 4−, PO 4 3−, SO 4 2−, ClO 4 −, ca… The basicity of an oxide glass can be measured experimentally from the frequenc…

Optical basicity and refractivity of aluminosilicate glasses

WebApr 11, 2024 · Optical sensors with distinct colorimetric output upon binding with fluoride offer a convenient, fast and reliable methodology for its on-site detection. ... The basicity of these anions in DMSO medium results in deprotonation of the acidic N-H moieties of R leading to the appearance of the new charge-transfer peak at 450nm. In addition, the ... WebJan 1, 2024 · The optical basicity of prepared glasses decreased with the increasing concentration of lanthanum oxide. Metallization criterion on the basis of refractive index showed an increasing trend while energy band gap based metallization criterion showed a decreasing trend. dutch central america flag https://hlthreads.com

The influence of basicity on oxygen activity and antimony oxide f ...

WebMar 13, 2024 · A brief study on optical and mechanical properties of an organic material: Urea glutaric acid (2/1)-a third order nonlinear optical single crystal. Crystals 2024, 11, 1239. [Google Scholar] Dimitrov, V.; Sakka, S. Electronic oxide polarizability and optical basicity of simple oxides. J. Appl. Phys. 1996, 79, 1736–1740. WebThe concept of optical basicity (Λ) is particularly suited to binary oxides and oxidic network materials such as silicates to characterize the acid–base nature of glasses and melts and to account for the complexation of metal cations by a variety of anionic frameworks. dutch chain approach

Frontiers Influence of Optical Basicity on Cu+ Luminescence in ...

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Optical basicity

Optical Basicity - Encyclopedia of Glass Science, …

WebThe optical basicity Λ has been evaluated depends on the optical band gap and the refractive indexdata for two different ternary glass systems. Also the uncertainty of Λ in the two cases was estimated, hence we can predict … WebFeb 25, 2002 · The electronic polarizability and optical basicity of La 2 O 3 and related glasses have been determined from ultraviolet absorption spectra and calculations based …

Optical basicity

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WebApr 8, 2024 · Physical properties were studied such as; X-ray diffraction, FTIR spectra, and UV–visible transmission. The optical basicity, average electro negativity have been estimated. The estimated... WebAug 1, 2024 · Optical bandgap energy, refractive index, molar polarizability, molar electronic polarizability, electronic polarizability, and bandgap based oxide ion polarizabilities, optical basicity, electric susceptibility, and other important parameter were reported in this work.

WebDec 20, 2024 · Titanium-doped and titanium-free lithium borate glasses were prepared using a quenching method and high-purity-grade chemical substances. Structural analysis was carried out by Fourier transform infrared (FT-IR) spectroscopy and mechanical measurement. The states of the produced glasses were examined by x-ray diffraction, and … WebHello Kai Fauth, Slag Basicity is a measure of the acidic-basic character of the oxides, widely used by the glass scientists, slag metallurgists and some geologists as well. You will get …

WebRefractivity data for aluminosilicate glasses (densities and refractive indices) have been used to examine the relationship between oxygen polarisability, alpha (O2-), and optical basicity, and also to calculate the basicity moderating parameter of … WebMay 26, 2015 · A new sulfide capacity model for CaO-Al 2 O 3 -SiO 2 -MgO slags has been developed based on corrected optical basicity. The present model has taken charge compensation into consideration and postulated that Al exits in the form of [1/2Ca (AlO 4 )] 4– when NCaO is higher than NAl2O3 in slag.

WebThe optical basicity of the manufactured glass samples is increased from 0.577 to 0.862, which is a significant improvement. As the quantity of oxygen atoms in the produced glass samples diminishes, the oxygen packing density varies between 102.978 and 78.351, depending on the sample size. The energy of the optical band gap ranges between 3.878 ...

WebApr 12, 2024 · Few reports exist on the effect of the basicity of refining slag on inclusions in 15-5PH stainless steel and its removal efficiency. In this study, the effects of various basicities on the formation and removal efficiency of inclusions in molten steel were investigated. To investigate the effect of the chemical makeup of slag on the non-metallic … dutch central governmentWebOct 10, 2024 · Optical basicity is identified as the average electron donor power of a fluorinated or oxidic compound ( Herrmann et al., 2015 ). For a glass system consisting of fluorinated and oxidic compounds, the optical basicity can be estimated based on Duffy's empirical formula ( Sontakke and Annapurna, 2012; Zheng et al., 2014; Guo et al., 2024 ), dutch centre backsWebFinding a parameter of the same type for solid oxides was not so easy. Modern theories of reactivity propose to consider the oxidizing power, acidity, basicity, and reducing power, as steps along a same continuum, instead of distinct phenomena [3]. Among parameters, Zhang’s scale of electronegativity [4], optical electronegativity and optical ... cryptopunk 2077WebOptical basicity Λth being a characteristic of bulk oxide, a scale of surface optical basicity, Λsurf is proposed by plotting the XPS O1s binding energy against Λth, which results in a … cryptopunk #7804WebFeb 1, 2024 · The concept of optical basicity (Λ) is particularly suited to binary oxides and oxidic network materials such as silicates to characterize the acid–base nature of glasses … cryptopunk #2338 nftWebMar 16, 2024 · Transmetalation is accompanied by relevant optical absorption changes and quenching of the fluorescence emission, leading to high selectivity and sensitivity of the chemosensor, with the advantage of not requiring any sample pretreatment or pH adjustment. ... Transmetalation is strongly influenced from the Lewis basicity of the … cryptopunk #8334 soldWebApr 15, 2007 · This relationship presents a general trend toward an increase in the oxide ion polarizability with increase in optical basicity. The Λ values estimated from α O 2-using Eq. (6) are given in Table 1 (columns 9–10). Large α O 2-(n) values over 2 Å 3 and large Λ values over 1.0 are obtained. That is, the rare earth oxides showing electronic polarizability … cryptopunk 1889